"chemistry, physics and technology of surface"   2008

 

contents

 

 

Page

Preface

5

Theory of chemical structure and reactivity. Simulation of surface processes

1.

A COMPARISON OF SURFACE COMPLEXATION MODELS FOR QUANTITATIVE DESCRIPTION OF ACIDIC PROPERTIES OF FUMED SILICA

N.N. Vlasova 

                   

6

2.

A THEORETICAL STUDY ON THE INTERACTION BETWEEN SILICA SURFACE AND HYDROGEN FLUORIDE AQUEOUS SOLUTIONS

А.А. Kravchenko, А.G. Grebenyuk, V.V. Lobanov

                     

16

3.

A QUANTUM CHEMICAL ANALYSIS OF ASCORBIC ACID OXIDATION AS MOLECULAR AND DISSOCIATED FORMS ON SILICA SURFACE.

E.M. Demianenko, A.G. Grebenyuk, V.V Lobanov

                   

22

4.

INTERACTION OF Γ‑AMINOPROPYLTRIETOXYSILANE WITH HYDROXYLATED MAGNETITE SURFACE: QUANTUM CHEMICAL CALCULATIONS.

А.М. Datsyuk, L.P. Storozhuk, V.V. Lobanov, P.P. Gorbyk 

                     

31

5.

MODELING OF THE INTERACTIONS BETWEEN DEFECT VANADIUM DIOXIDE SURFACE AND WATER AND/OR ETHANOL MOLECULES.

V.N. Kaurkovskaya, A.G. Grebenyuk, V.V Lobanov 

                     

37

6.

ROLE OF SURFACE ATOMIC STRUCTURE IN FORMING A POTENTIAL WITHIN VACUUM INTERVAL BETWEEN NEARLY SEPARATED METAL AND SEMICONDUCTOR.

L.G. Il’chenko, V.V. Lobanov 

                   

43

7.

KINEMATIC FEATURES OF DIPOLE PHOTOMOTORS.

T.Ye. Korochkova, M.L. Dekhtyar, V.M. Rozenbaum 

                     

52

8.

THERMALLY STIMULATED DEPOLARIZATION OF DIPOLE ROTATOR IN SYMMETRIC POTENTIAL OF HINDERED ROTATION.

O.Ye. Tsyomyk (Vovchenko), V.E. Klymenko, V.M. Rozenbaum

                   

61

9.

SURFACE EXCITATIONS OF SPHEROID. GENERAL CASE. 

B.N. Gorshkov, L.G. Grechko, E.Yu. Grischuk

                     

67

10.

INVERSE TASKS OF OPTICAL AND DIELECTRIC SPECTROSCOPY OF NANOPARTICLE SUSPENSIONS AND DEWY POROUS MEDIA.

L.B. Lerman, М.А. Lyuschenko, Ya.S. Krivoruchko, N.G. Shkoda, S.V. Shostak 

                   

73

11.

ONSET OF ADDITIONAL PLASMON RESONANCES IN SMALL SHEATHED PARTICLES.

L.B. Lerman

                   

91

12.

DIFFUSION OF THE PARTICLES WITH INTERNAL DEGREES OF FREEDOM IN DISORDERED MEDIUM.

V.P. Shkilev, V.V. Lobanov, P.Е. Stryzhak

                   

101

13.

TRANSFER OF ELECTROMAGNETIC IRRADIATION IN AEROSOL-DISPERSE MEDIA.

L.G. Grechko, E.Yu. Grischuk, A.M. Zavalov

                   

108

Physics and chemistry of surface phenomena

14.

THE ELECTROPHYSICAL PROPERTIES OF POLYMER – IONIC CONDUCTOR SYSTEMS IN SUPER-HIGH FREQUENCY BAND.

S.M. Makhno  

                   

115

15.

IRREVERSIBLE CAPACITY LOSSES UPON LITHIUM INSERTION/EXTRACTION IN GRAPHITE – SILICON ELECTRODES

S.P. Kuksenko

                   

123

16.

ADSORPTION EQUILIBRIA OF VOLATILE ORGANIC COMPOUNDS ON THE SURFACE OF ATMOSPHERIC AEROSOL COMPONENTS.

V. I. Bogillo

                   

129

17.

KINETIC PROPERTIES OF POLYTETRAFLUORОETHYLENE – CARBON NANOTUBE COMPOSITES.

О.М. Garkusha, S.N. Маkhnо, G.P. Prikhod’ko, Yu.I. Sementsov 

                   

140

18.

STRUCTURAL AND MECHANICAL PROPERTIES OF WATER DISPERSIONS OF FUMED SILICA WITH NON-IONOGENIC POLYMERS.

E.V. Goncharuk, L.S. Andriyko, M.L. Malyscheva,  V.F. Grutsenko, V.I. Zarko, V.M. Gun’ko 

                   

147

19.

CLUSTER MODELS FOR OXIDIZED COAL SURFACE AND THEIR ELECTROCHEMICAL PROPERTIES.

V.S.Kuts, S.A.Kopyl, Yu.A.Tarasenko

 

                   

156

20.

QUANTUM EFFECTS IN MULTILAYER SI-GE NANOHETEROSTRUCTURES

Yu.N. Kozyrev, M.Yu. Rubezhanska, A.V. Sushyі, S.V.Kondratenko, O.V. Vakulenko, A.A. Da­dykin, A.G. Naumovets 

                   

176

21.

FORMATION OF THE ZNXCD1-XTE SOLID SOLUTION SINGLE CRYSTAL POLISHED SURFACES WITH THE HNO3–HBR–ETHYLENE GLYCOL ETCHANTS.

V.М. Tomashik, G.M. Okrepka, Z.F. Tomashik, P. Moravec, P. Höschl

                   

186

22.

ADSORPTION OF ALIPHATIC CARBOXYLIC ACIDS ON SILICA SURFACE.

L.R. Azizova, B.B Palyanitsa, O.O. Kazakova, T.V. Kulik

                   

193

23.

ADSORPTION OF CHITOSAN ON MIXED SILICA SURFACES.

T.V. Borodavka, B.B. Palyanytsya, Т.V. Kulik

                   

200

24.

DECOMPOSITION OF YHX POWDERS UNDER CONDITIONS OF STEP-BY-STEP HEATING IN AIR.

V.V. Garbuz, V.A. Petrova, A.V. Yakovlev, S.V. Nuzhda, L.N. Kuzmenko, R.A. Morozova, V.D. Kurochkin, V.V. Skorokhod, Yu.M. Solonin

                   

206

25.

SORPTION OF CE(III) BY CLAY MINERALS.

G.N. Pshinko, S.А. Kobec, А.А. Bogolepov, I.А. Коvаlchuk

                   

210

26.

ADSORPTION PROPERTIES OF ANISOTROPIC NANOPARTICLES OF LAYER MOLYBDENUM DISULFIDE AND TUNGSTEN DISULFIDE.

L.М. Kulikov, N.B. König, N.V. Shevchuk, V.V. Garbuz

                   

217

27.

DEVELOPMENT OF BROWN COAL POROSITY UNDER THERMOLYSIS WITH ALKALIS OF DIFFERENT NATURE.

Yu.V. Tamarkina, L.A. Bovan, N.N. Tsyba, V.A. Kucherenko

                   

224

28.

INFLUENCE OF SURFACE STRUCTURE OF SILICA ADSORBENTS ON THEIR CONDUCTING PROPERTIES. 

Yu.S. Dzyaz’ko, L.A. Belyakova

                   

230

29.

EFFECT OF FRACTAL DIMENSION OF BULK CATALYSTS ON ACTIVATION ENERGY OF HETERO­GENEOUS CATALYTIC CO OXIDATION.

A.I. Trypolski, T.M. Gurnyk, P.E. Stryzhak

                   

238

30.

ΑCID-BASE PROPERTIES OF 3‑AMINOPROPYL-CONTAINING XEROGELS.

V.P. Goncharyk, L.I. Kozhara, Yu.L. Zub

                   

248

31.

CHEMICAL IMMOBILIZATION OF b‑CYCLODEXTRIN ON HALOGENOALKYLSILICA SURFACES.

N.V. Roik, А.М. Varvarin

                   

257

32.

DESIGN OF EFFECTIVE COPPER-CERIUM-ZIRCONIUM CATALYST FOR SELECTIVE CO OXIDATION IN HYDROGEN‑RICH MIXTURES.

P.Е. Stryzhak, G.R. Kosmambetova, E.М. Moroz, А.V. Guralskiy, R.I. Gulyaev, V.P. Pakharukova, А.I. Boronin, V.I. Gritsenko

                   

264

Nanomaterials and nanotechnologies

33.

A STUDY ON PECULIARITIES OF PHYSICO-CHEMICAL FORMATION PROCESSES OF NANOSIZED ZNO WHISKERS. 

P.P. Gorbyk, I.V. Dubrovin, Yu.O. Demchenko, M.M. Filonenko, O.A. Dadykin

                   

275

34.

FORMATION OF HOLLOW MAGNETITE NANOSPHERES.

P.P. Gorbyk, I.V. Dubrovin, Yu.O. Demchenko, M.M. Filonenko,Н.В. Абрамов

 

                   

282

35.

DESINGN OF MERCURY (II) ADSORPTION SITES ON HIGH DISPERSE SILICA SURFACE.

L.A. Belyakova, D.Yu. Lyashenko, O.M. Shvets

 

                   

288

36.

ABOUT SI – O – FE BOUNDS IN IRON OXIDE – SILICA NANOCOMPOSITES.

V.M. Bo­gatyrov, M.V.Galaburda, L.P. Storozhuk, E.I. Oranskaya, O.M. Korduban, P.P. Gorbyk

                   

296

37.

ON THE EFFECT OF SILICA MATRIX ON THE STRUCTURE OF IRON OXIDE OBTAINED BY THERMOLYSIS OF IRON (III) ACETYLACETONATE IN THE NANOCOMPOSITES BASED ON FUMED SILICA.

O.I. Oranska, Yu.I. Gornikov, V.M. Bogatyrov, E.V. Polshin, M.V. Galaburda

                   

304

38.

PROPERTIES OF NANOSIZED CERIUM AND COPPER OXIDE MATERIALS PREPARED FROM CITRATE SOLUTIONS.

I.A. Farbun, I.V. Romanova, S.A. Kirillov

                   

311

39.

VOLTAMMETRIC DETERMINATION OF BIOGENIC AMINES ON THE ELECTRODES OF CARBON NANOTUBES MODIFIED WITH POLYANILINE.

G.М. Zagorovskiy, I.G. Sydorenko, N.M. Vlasova, V.V. Lobanov

                   

317

40.

SILICA CARRIERS FOR CONTROLLED RELEASE OF ACTIVE MATTER

R.B. Kozakevych, Y.M Bolbukh. V.A. Tertykh

                   

325

41.

MODIFICATION OF NANOSILICA BY LOW VOLATILE SILANES IN PSEUDO-LIQUID STATE.

I.G. Telegeev, E.M. Pakhlov, E.F. Voronin

                   

332

42.

COMPOSITION OF TIHX UNDER ISOTHERMAL CONDITIONS OF STEP-BY-STEP HEATING IN AIR.

V.V. Garbuz, V.A. Petrova, A.V. Yakovlev, S.V. Nuzhda, L.N. Kuzmenko, R.A. Morozova, V.D. Kurochkin, V,V, Skorokhod, Yu.M. Solonin

                   

339

43.

PREPARATION AND PROPERTIES OF THE PHOTOCATALYTIC-ACTIVE MEMBRANE WITH IMMOBILIZED TIO2 FOR WATER TREATMENT FROM PHENOL AND ITS DERIVATIVES. 

E.A. Rolya, V.M. Kochkodan, V.V. Goncharuk

                   

344

44.

SYNTHESIS AND PROPERTIES OF THE MICRO/MESOPOROUS MATERIALS IN THE TERNARY SYSTEMS TIO2–AL2O3–SIO2.

K.M. Khomenko, A.V. Redkina1, O.I. Oranska, M.M. Tsyba

                   

354

45.

PECILIARITIES OF TITANIUM INCLUSION INTO SBA-15-TYPE SILICEOUS MESOPOROUS MOLECULAR SIEVES THROUGH THEIR TEMLATE SYNTHESIS.

A.S. Kovalenko, V.I. Litvin, V.G. Ilyin

                   

362

46.

EFFECT OF MECHANOCHEMICAL ACTIVATION ON SORPTION PROPERTIES OF RAW MINERALS.

T.S. Psareva, O.I. Zakutevskyy, I.V. Bachericova, K. Wieczorek–Ciurowa

                   

371

47.

STRUCTURE AND MAGNETIC PROPERTIES OF MAGNETITE/SILICON DIOXIDE NANOCOMPOSITES.

L.S. Semko, P.P. Gorbyk, M.V. Abramov, O.G. Sirenko, I.V. Dubrovin, O.I. Oranska

                   

374

48.

ELECTRO- AND PHOTOCATALYTIC PROPERTIES OF ELECTRODES BASED ON MESOPOROUS TIO– ZNO – AG FILMS.

V. Vorobets, E. Manuilov, N.Smirnova, Yu. Gnatyuk, G. Kolbasov, A.Eremenko

                   

382

49.

EFFECT OF SILICA MATRIX MORPHOLOGY ON FORMATION OF NANOZIRCONIA.

I.Ya. Sulim, M.V. Borysenko, V.M. Gun’ko

                   

391

50.

INFLUENCE OF MAGNETIC FIELD ON SENSOR CHARACTERISTICS OF COMPOSITE MATERIALS BASED ON NANOCRYSTALLINE NICKEL.

L.S. Semko, O.I. Kruchek, P.P. Gorbyk, Yu.A. Shevlyakov

                   

398

51.

MATRIX SYNTHESIS, STRUCTURAL AND ADSORPTION PROPERTIES OF POROUS POLYMERIC MATERIALS.

M.V. Opanasenko

                   

407

52.

A DEVELOPMENT OF ECOLOGICALLY PURE TRIAL TECHNOLOGY OF NANODISPERSE OXIDE PRODUCTION.

U.S. Tarasevich, P.P. Gorbyk

                   

414

53.

USAGE OF SUSPENSIONS BASED ON FUMED SILICA FOR MECHANO- CHEMICAL POLISHING OF SINGLE-CRYSTALLINE SILICON.

V.E. Gaishun, Y.A. Kosenok, O.I. Tyulenkova, V.V. Turov, V.M. Gun’ko

                   

423

54.

MODIFICATION OF THE OUTER SURFACE OF ZEOLITE CRYSTALS – A WAY TOWARDS THE INCREASE OF THEIR CATALYTIC EFFICIENCY.

Yu.G. Voloshyna, I.A. Repetskiy, L.K. Patrylak, K.I. Patrylak

                   

429

55.

MOULDED NANOMATERIALS BASED ON ACTIVE COALS FROM THE WASTES OF POLYETHYLENETEREPHTALATE.

Yu.G. Voloshina, I.A. Repetskiy, L.K. Patrylyak, K.I. Patrylyak

                   

437

Medical and biological aspects of surface phenomena

56.

HYDRATE STRUCTURES IN PARTIALLY DEHYDRATED BONE MARROW CELLS AS STUDIED BY 1H NMR SPECTROSCOPY.

V.V. Turov, S.V. Kerus, V.M. Gun’ko

                   

443

57.

TEMPERATURE-PROGRAMMED DESORPTION MASS SPECTROMETRY OF BOVINE SERUM ALBUMIN IN CONDENSED STATE AND AS ADSORBED ON DISPERSE OXIDE SURFACES.

N.Y. Klymenko, N.P. Galagan, B.G. Mischanchuk, V.I. Zarko, V.O. Pokrovskiy

                   

456

58.

 SUPRAMOLECULAR EFFECTS IN HYDRATED MEAL.

V.I. Zarko, G.E. Polischuk, O.N. Rybak, E.V. Goncharuk, V.A. Mikhaylik, V.F. Gritsenko, V.M. Gun’ko

                   

467

59.

GELATIN ADSORPTION ON HIGH DISPERSE SILICA CONTAINING VITAMINS.

I.B. Bazhura, I.V. Laguta, O.A. Kazakova, O.N. Stavinskaya, P.A. Kuzema

                     

478

60.

ANTIOXIDANT PROPERTIES OF SOME FLAVONOL DERIVATIVES. \I.V. Laguta, O.N. Stavinskaya, Yu.О. Кaydalova, Т.І. Yushchenko, O.A. Kazakova, V.G. Pivovarenko

                   

483

61.

ADSORPTION OF DIPEPTIDES ONTO FUMED SILICA SURFACE FROM AQUEOUS SOLUTIONS.

N.N. Vlasova, O.V. Markitan, L.P. Golovkova

                   

488

62.

CLUSTERIZATION OF WATER BOUND IN FROZEN-DRIED BOVINE GAMETES CONTAINING ORGANIC ADDITIVES.

V.V. Turov, N.P. Galagan, V.M. Gun’ko, S.I. Kovtun, S.V. Kerus, N.Y. Klymenko, A.V. Turov

                   

494

63.

MAGNETOCARRIED BIOACTIVE NANOCOMPOSITES.

P.P. Gorbyk, A.L. Petranovska, D.G. Usov, L.P.Storozhuk,V.F. Chehun, N. Y. Lukyanova, S.I. Shpileva

                   

502

64.

A STUDY ON THE NATURE OF NANOSILICA EFFECT ON CELLUAR OBJECTS. 

T.V. Krupska, V.N. Barvinchenko, V.V. Turov

                   

511

65.

BACTERICIDE PROPERTIES OF GOLD AND SILVER NANOPARTICLES IN SOLUTION AND ON HIGH DISPERSE SILICA SURFACE.

G. Yashan, G. Krylova, A. Eremenko, N. Smirnova, V. Zhalko-Tytarenko, V. Marievskiy, I. Chekman

                   

524

66.

INTERACTION OF ACETIC ACID AND TARTARIC ACID WITH NATURAL MINERALS.

N.P. Galagan, V.M. Bogatyrov, B.A. Ivanitskaya, V.A. Pokrovskiy, N.V. Zaimenko

                   

534

67.

EFFECT OF COLLOIDAL SILVER ON VEAST CELLS.

S.P. Turanska, V.V. Yanishpolskiy, V.V. Turov, P.P. Gorbyk

                   

541

68.

BIOFUNCTIONALIZATION OF THE SURFACE OF MAGNETOCARRIED  NANOCOMPOSITES BY HUMAN IMMUNOGLOBULINE.

D.G. Usov, A.L. Petranovska, P.P. Gorbyk, M.P. Ivakhnenko

                   

548

69.

A STUDY ON CITOTOXICITY OF CARBON NANOTUBES BY SPIN PROBE METHOD.

N.T Kartel,V.I. Grischenko, V.P. Cherhykh, L.V. Ivanov, O.A. Nardid, Yu.I. Sementsov, G.P. Prikhod’ko, S.N. Kovalenko, Yu.I. Gubin, S.,V.Repina

                   

557

70.

CONCEPTION FOR METHODOLOGY OF IDENTIFICATION AND TOXICOLOGICAL TESTS OF NANOMATERIALS AND EVALUATION OF RISKS FOR HUMAN ORGANISM AND ENVIRONMENT AT THEIR PRODUCTION AND APPLICATION.

М.Т. Kartel, V.P. Теrеschenko

                   

562

 

Personalia

 

60th Birthday of Corresponding Member of National Academy of Sciences of Ukraine M.T. Kartel

 

584

 

70th Birthday of Professor A.M. Eremenko

 

586

 

70th Birthday of Professor L.G. Grechko

 

588

 

70th Birthday of Professor Yu.I. Tarasenko

 

590

 

 List of Reviewers

592