Хітозан та його похідні, як ефективні сорбенти для вилучення йонів металів

  • T. M. Budnyak Інститут хімії поверхні ім. О.О. Чуйка Національної академії наук України
  • V. A. Tertykh Інститут хімії поверхні ім. О.О. Чуйка Національної академії наук України
  • E. S. Yanovska Київський національний університет імені Тараса Шевченка

Анотація

В огляді проаналізовано фізико-хімічні характеристики та адсорбційні властивості природного полімеру хітозану та його модифікованих форм щодо йонів металів. Розглянуто механізми адсорбційної взаємодії та йонного обміну за участю функціональних груп хітозану та його похідних з метою створення на їх основі ефективних адсорбентів для вилучення металів з водних розчинів.

Посилання

Wu F. Ch., Tseng R.L., Juang R.S. A review and experimental verification of using chitosan and its derivatives as adsorbents for selected heavy metals // J. Environ. Manage. – 2010. – V. 91. – P. 798–806.

Popuri S. R., Vijaya V., Boddu V.M., Abburi K. Adsorptive removal of copper and nickel ions from water using chitosan coated PVC beads // Bioresour. Technol.   – 2009. – V. 100. – P. 194–199.

Kolodynska D. Adsorption characteristics of chitosan modified by chelating agents of a new generation // Chem. Eng. J. – 2012. – V. 179. – P. 33–43.

Ravi Kumar Majeti N. V. A review of chitin and chitosan applications // React. Funct. Polym. – 2000. – V. 46. – P. 1–27.

Grini G. Recent development in polysaccharide-based materials used as adsorbents in wastewater treatment // Prog. Polym. Sci. – 2005. – V. 30. – P. 38–70.

Vårum K.M, Anthonsen M.W., Grasdalen H., Smidsrød O. Determination of the degree of N-acetylation and the distribution of N-acetyl groups in partially N-deacetylated chitins (chitosans) by high-field n.m.r. spectroscopy // Carbohydr. Res. – 1991. – V. 211. – Iss. 1. – P. 17–23.

Ottøy M. H., Vårum K. M., Smidsrød O. Compositional heterogeneity of chitosans // Carbohydr. Polym. – 1996. – V. 29. – P. 17–24.

Duarte M. L., Ferreira M. C., Marvão M. R., Rocha J. An optimized method to determine the degree of acetylation of chitin and chitosan by FTIR spectroscopy // Int. J. Biol. Macromol. – 2002. – Vol. 31. – P. 1–8.

Ogawa K., Yui T. Crystallinity of partially N – acetylated chitosan // Bioscience, Biotechnology, Biochemistry – 1993. – Vol. 57. – Iss. 9. – P.1466–1469.

Okuyama K., Noguchi K., Miyazawa R., Yui T., Ogawa K. Molecular and crystal structure of hydrated chitosan // Int. J. Biol. Macromol. – 1997. – Vol. 30. – Iss. 19. – P. 5849–5855.

Milot C., McBrien J., Allen S., Guibal E. Influence of Physicochemical and Structural of hydrated chitosan // J. Appl. Polym. Sci. – 1998. – Vol. 68. – Iss. 4. – P. 571–580.

McKay G., Blair H. S., Grant S. Desorption of copper from a copper-chitosan complex // J. Chem. Technol. Biotechnol. – 1987. – Vol. 40. -  Iss. 1. – P. 63–74.

Domard A. pH and c.d. measurements on fully deacetylated chitosan: application to Cu(II)–polymer interactions // Int. J. Biol. Macromol. – 1987. – Vol. 9. – P. 98–104.

Gonzalez-Davila M., Santana-Casiano J. M., Millero F. J., The Adsorption of Cd(ll) and Pb(ll) to Chitin in Seawater // J. Colloid Interf. Sci. – 1990. – V. 137. – 102-110.

Erosa M. S. D., Medina T. I. S., Mendoza R. N., Rodriguez M. A., Guibal E. Cadmium sorption on chitosan sorbents: kinetic and equilibrium studies // Hydrometallurgy – 2001. – Vol. 61. – Iss. 3. – 157–167.

Debbaudt A. L. Ferreira M. L., Gschaider M. E. Theoretical and experimental study of M2+ adsorption on biopolymers III: comparative kinetic pattern of Pb, Hg and Cd // Carbohydr. Polym. – 2004. – Vol. 56. – P. 321–332.

Chassary P., Vincent T., Guibal E. Metal anion sorption on chitosan and derivative materials: a strategy for polymer modification and optimum use // React. Funct. Polym. – 2004. – V. 60. – P. 137–149.

Grubal E. Interactions of metal ions with chitosan-based sorbents: a review // Sep. Purif. Technol. – 2004. – V. 38. – P. 43–74.

Roberts G. A. F. Chitin Chemistry. –London, UK: MacMillan, 1992, 350 p.

Cao Z., Ge H., Lai S. Studies on synthesis and adsorption properties of chitosan cross-linked by glutaraldehyde and Cu(II) as template under microwave irradiation // Eur. Polym. J. – 2001. – V. 37. – P. 2141–2143.

Capitani D., De Angelis A.A., Crescenzi V., Masci G., Segre A.L. NMR study, of a novel chitosan – based hydrogel // Carbohydr. Polym. – 2001 – Vol. 45, N 3. – P.245–252.

Paradossi G., Cavalieri F., Crescenzi V. 1H NMR relaxation study of a chitosan – cyclodextrin network // Carbohydr. Res. – 1997. – V. 300. – P. 77–84.

Kawamura Y., Mitsuhashi M., Tanibe H., Yoshida H. Adsorption of metal – ions on polyaminated highly porous chitosan chelating resin // Ind. Eng. Chem. Res. – 1993. – Vol. 32. – P. 386–391.

Alam M. S., Inoue K., Yoshizuka K. Ion exchangeradsorption of rhodium III from chloride media on some anion exchangers // Hydrometallurgy – 1998. – V. 49. – P. 213– 227.

Ohga K., Kurauchi Y., Yanase H. Adsorption of Cu2+ or Hg2+ ions on resins prepared by crosslinking metal – complexed chitosans // Bull. Chem. Soc. Jpn.   – 1987. – Vol. 60 – P. 444–446.

Mi L., Shyu S.S., Lee S.T., Wong T.B. Kinetic study of chitosan – tripolyphosphate complex reaction and acid – resistive properties of chitosan – tripolyphosphate gel beads prepared by in – liquid curing method // J. Polym. Sci. B: Polym. Phys. – 1999. – Vol. 37. – P. 1551–1564.

Li C. B., Hein S., Wang K. Biosorption of chitin and chitosan // Mater. Sci. Technol. – 2008. – Vol. 24. – N. 9. 1088–1097.

Hsien T.-Y., Rorrer G. L. Heterogeneous cross-linking of chitosan gel beads: kinetics, modeling, and influence on cadmium ion adsorption capacity // Ind. Eng. Chem. Res.        – 1997. – V. 36. – P. 3631–3638.

Inoue K., Yoshizuka K., Baba Y., Gebelein C., Carraher C., Biotechnology and Bioactive Polymers. ­– New York: Plenum Press, 1994. – P. 35–41.

Nagib S., Inoue K., Yamaguchi T., Tamaru T. Recovery of Ni from a large excess of Al generated from spent hydrodesulfurization catalyst using picolylamine type chelating resin and complexane types of chemically modified chitosan // Hydrometallurgy – 1999. – V. 51. – P. 73–85.

Inoue K., Ohto K., Yoshizuka K., Yamaguchi T., Tanaka  T. Adsorption of lead(II) ion on complexation types of chemically modified chitosan // Bull. Chem. Soc. Jpn. – 1997. – V. 70. – 2443–2447.

Ma F., Qu R., Sun Ch., Wang Ch., Ji Ch., Zhang Y., Yin P. Adsorption behaviors of  Hg(II) on chitosan functionalized by amino-terminated hyperbranched polyamidoamine polymers // J. Hazard. Mater. – 2009. – V. 172. – P. 792–801.

Varma A. J., Deshpande S. V., Kennedy J. F. Metal complexation by chitosan and its derivatives: a review // Carbohydr. Polym. – 2004. – V. 55. – P. 77–93.

Peniche-Covas C., Alvarez L.W., Argüelles W. - Monal The adsorption of Mercuric Ions by chitosan // J. Appl. Polym. Sci. – 1992. – V. 46. – P. 1147–1150.

Qian S., Huang G., Jiang J., He F., Wang Y. Studies of adsorption behavior of crosslinked chitosan for Cr(VI), Se(VI) // J. Appl. Polym. Sci. – 2000. – V. 77. – P. 3216–3219.

Pearson R. G. Hard and soft acids and bases // J. Am. Chem. Soc.      – 1963. – Vol. 5. – Iss. 22. – P. 3533–3539.

Marcus Y. Ion Properties. – New York, NY: Marcel Dekker Inc., 1997. – 259 p.

Muzzarelli R. A. A., Tanfani F., Emanuelli M., Marriotti S. The characterization of N-methyl, N-ethyl, N-propyl, N-butyl and N-hexyl chitosans, novel film-forming polymers // J. Membr. Sci. – 1983. – V. 16. – P. 295–308.

Schlick Sh. Binding Sites of Cu2+ in Chitin and Chitosan. An Electron Spin Resonance Study // Macromolecules – 1986. – V. 19. – P. 192–195.

Rhazi M., Desbrières J., Tolaimate A., Rinaudo M., Vottero P., Alagui A. Meray M. El. Influence of the nature of the metal ions on the complexation with chitosan. Application to the treatment of liquid waste // Eur. Polym. J. – 2002. – V. 38. – P. 1523–1530.

Nieto J.M., Peniche-Covas C., Del J. Bosque Preparation and characterization of a chitosan – Fe(III) complex // Carbohydr. Polym. – 1992. – V. 18. – P. 221–224.

Chiessi E., Paradossi G., Venanzi M., Pispisa B. Copper complexes immobrltzed to chitosan // J. Inorg. Biochem. – 1992. – V. 46. – P. 109–118.

Guibal E., Roulph C., Le Cloirec P. Infrared Spectroscopic Study of Uranyl Biosorption by Fungal Biomass and Materials of Biological Origin // Environ. Sci. Technol. Lett. – 1995. – V. 29. – P. 2496–2503.

Shahgholi M., Callahan J.H., Rappoli B.J., Rowley D.A. Investigation of Copper–Saccharide Complexation Reactions using Potentiometry and Electrospray Mass Spectrometry // Int. J. Mass Spectrom. – 1997. – V. 32. – P. 1080–1093.

Park J.W., Choi K.-H., Park K.K. Acid-Base Equilibria and related properties of chitosan // Bull. Korean Chem. Soc. – 1983. – V. 4. – No. 2. – P. 68–72.

Navarro R., Guzman J., Saucedo I., Revilla J., Guibal E. Recovery of metal ions by chitosan: sorption mechanisms and influence of metal speciation // Macromol. Biosci. – 2003. – V. 3. – P. 552–561.

Hirano S., Kondo Y., Nakazawa Y. Uranylchitosan complexes // Carbohydr. Res. – 1982. – V. 100. – P. 431–434.

Piron E., Domard A. Interaction between chitosan and uranyl ions. Part 2. Mechanism of interaction // Int. J. Biol. Macromol. – 1998. – V. 22. – P. 33–40.

Grubal E., Saucedo I., Roussy J., Le Cloirec P. Uptake of uranyl ions by new sorbing polymers: discussion of  adsorption isotherms and pH effect // React. Polym. – 1994. – V. 23. – P. 147–156.

Heras A., Rodriguez N.M., Ramos V.M., Agullo E. N-methylene phosphonic chitosan: a novel soluble derivative // Carbohydr. Polym. – 2001. – V. 44. – P. 1–8.

Sorlier P., Denuzière A., Viton C., Domard A. Relation between the degree of acetylation and the electrostatic properties of chitin and chitosan // Biomacromolecules – 2001. – V. 2. – P. 765 – 772.

Inoue K., Yoshizuka K., Baba Y. New developments in ion exchange. Materials, fundamentals, and applications // In: Proceedings of the International Conference on Ion Exchange, ICIE’91, Tokyo, Japan, Kodansha, Ltd. – 1991. – P. 543–548.

Guibal E., Milot C., Roussy J. Molybdate sorption by cross-linked chitosan beads: dynamic studies // Water Environ. Res. – 1999. – V. 71. – P. 10–17.

Ruiz M., Sastre A. M., Guibal E. // Palladium sorption on glutaraldehyde-crosslinked chitosan / React. Funct. Polym. – 2000. – V. 45. – P. 155–173.

Guibal E., Larkin A., Vincent T., Tobin J. M. Chitosan sorbents for platinum sorption from dilute solutions // Ind. Eng. Chem. Res. – 1999. – V. 38. – P. 4011–4022.

Guibal E., Von N., Sweeney O., Vincent T., Tobin J. M. Sulfur derivatives of chitosan for palladium sorption // React. Funct. Polym. – 2002. – V. 50. – P. 149–163.

Guzman J., Saucedo I., Navarro R., Revilla J., Guibal E. Vanadium Interactions with Chitosan: Influence of Polymer Protonation and Metal Speciation // Langmuir – 2002. – V. 18. – P. 1567–1573.

Ruiz M., Sastre A., Guibal E. Pd and Pt recovery using chitosan gel beads. II. Influence of chemical modifications on sorption properties // Sep. Sci. Technol. – 2002. – V. 37. – Iss. 10. – P.  2385–2403.

Lasko C. L., Hurst M. P. An investigation into the use of chitosan for the removal of soluble silver from industrial wastewater // Environ. Sci. Technol. – 1999. – V.  33. – P. 3622–3626.

K.-D. Vorlop, Klein J. Formation of spherical chitosan biocatalysts by ionotropic gelation // Biotechnol. Lett. – 1981. – V. 3. - No. 1. – P. 9–14.

Draget K. I., Varum K. M., Moen E., Gynnild H., Smidsrod O. Chitosan cross-linked with Mo(VI) polyoxyanions: a new gelling system // Biomaterials – 1992. – V. 13. – P. 635– 638.

Guibal E., Milot C., Roussy J. Influence of hydrolysis mechanisms on molybdate sorption isotherms using chitosan // Sep. Sci. Technol. – 2000. – V. 35. – P. 1021–1038.

Guibal E., Vincent T., Mendoza R. N., Synthesis and characterization of a thiourea derivative of chitosan for platinum recovery // J. Appl. Polym. Sci.– 2000. – V. 75. – P. 119–134.

Juang R.-Sh., Ju C.-Y., Equilibrium sorption of copper(II)-Ethylenediaminetetraacetic acid chelates onto cross-linked, polyaminated chitosan beads // Ind. Eng. Chem. Res. – 1997. – V. 36. – P. 5403–5409.

Wu F.C., Tseng R.L., Juang R.S. Role of pH in metal adsorption from aqueous solutions containing chelating agents on chitosan // Ind. Eng. Chem. Res. – 1999. – V. 38. – P. 270–275.

Juang R.-S., Shiau L.-D. Ion exchange equilibria of metal chelates of ethylenediaminetetraacetic acid (EDTA) with Amberlite IRA-68 // Ind. Eng. Chem. Res. – 1998. – V.  37. – P. 555–563.

Опубліковано
2013-09-06
Як цитувати
Budnyak, T. M., Tertykh, V. A., & Yanovska, E. S. (2013). Хітозан та його похідні, як ефективні сорбенти для вилучення йонів металів. Поверхня, (5(20), 118-134. вилучено із http://surfacezbir.com.ua/index.php/surface/article/view/511
Розділ
Фізико-хімія поверхневих явищ