Явища на межах поділу під впливом морфології та техтури вуглецевих матеріалів та їніх композитів
Анотація
Вуглецеві матеріали (ВM) можуть характеризуватися різною морфологією твердих частинок, текстурою, структурою поверхні (наприклад, ступенем окислення/відновлення) та іншими характеристиками. Тому пошук закономірностей численних ВМ, що стосуються міжфазних явищ, включаючи сорбцію з різних фаз, може бути складним завданням. Для з'ясування сутнісних аспектів явищ можуть бути використані різні експериментальні (наприклад, електронна мікроскопія, сорбція, спектроскопія, рентгенівська дифракція, термогравіметрія тощо) та теоретичні (наприклад, квантова хімія) методи з використанням розроблених обчислювальних методів. Тут були проаналізовані десятки ВM і композитів щодо (i) морфології твердих частинок, текстурних і поверхневих характеристик; (ii) сорбції органічних і неорганічних сполук, розчинених речовин/елюатів у різних середовищах; та (iii) ефектів обмеженого простору та кріоскопічних ефект для окремих та змішаних розчинників залежно від температури (при T < Tf) та концентрацій. Отримані результати становлять інтерес як з теоретичної, так і з практичної точок зору, оскільки показують різні аспекти міжфазних явищ, що відбуваються в поровому просторі різних ВМ і композитів, що характеризуються різною морфологією, текстурою і структурою поверхні. Це важливо для оптимізації характеристик ВМ для ефективного використання їх у практичних застосуваннях.
Посилання
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