Preparation and properties of the photocatalytic-active membrane with immobilized TiO2 for water treatment from phenol and its derivatives

  • E. A. Rolya A.V. Dumansky Institute of Colloid Chemistry and Water Chemistry of National Academy of Sciences of Ukraine
  • V. M. Kochkodan A.V. Dumansky Institute of Colloid Chemistry and Water Chemistry of National Academy of Sciences of Ukraine
  • V. V. Goncharuk A.V. Dumansky Institute of Colloid Chemistry and Water Chemistry of National Academy of Sciences of Ukraine

Анотація

A method of preparation and properties of a photocatalytic-active membrane with deposited TiO2 for water treatment from phenol and its derivatives have been developed and studied in the work. Ceramic membrane based on γ-Al2O3 was found to be the optimum porous support for immobilization of the catalyst. The comparison of various approaches for deposition of TiO2 active layer on the porous ceramic support was performed. It has been shown that the catalytic-active membrane obtained provides a high degree of water purification (99.4 – 99.9 %) not on­ly from phenol, but also from its derivatives (hydroquinone, p-chlorophenol, and n-nitrophenol) at rather short time of water treatment (1.5 – 2 h). The efficiency of water purification was found to depend essentially on solution pH value.

Посилання

Baird C. // Environ. Chem., Freeman, New York, 1998.

Шевченко, Марченко П.В., Таран П.Н., Лизунов В.В. Окислители в технологии водообработки. – Киев: Наук. думка, 1979. – 177 с.

Очистка природных вод от органических примесей сочетанием озонирования с УФ-облучением / В.В. Гончарук, В.Ф. Вакуленко, А.Н. Сова, Л.М. Олейник // Химия и технология воды. – 2004. – Т. 26, № 1. – С. 34 – 49.

Larachi F., Ihuta I., Belkacemi K. Catalytic wet air oxidation with a deactivating catalyst analysis of fixed and sparged three-phase reactors// Catal. Today. – 2001. – V. 64, № 3-4. – P. 309 – 320.

Reckhow D.A., Singer P.C. Evaluation of Chlorinated By-Products in Orinking Waters of Clentral // J. Amer. Water Works Assoc. – 1990. – V. 82, № 4. – P. 173 – 180.

Cooper C., Burch R. /An investigation of catalytic ozonation for the oxidation of halocarbons in drinking water preparation// Water Res. – 1999. – V. 33, № 18. – P. 3695 – 3700.

Hybrid processes coupling photocatalysis and membranes for degradation of organic pollutants in water / R. Mollinari, M. Borgese, E. Drioli, L. Palmisano, M. Schiavello // Catal. Today. – 2002. – V. 75. – P. 77 – 85.

Heterogeneous photocatalytic degradation of pharmaceuticals in water by using polycrystalline TiO2 and a nanofiltration membrane reactor / R. Molinari, F. Pirillo, V. Loddo, L. Palmisano // Catal. Today – 2006. – V. 118. – Р. 205 – 213.

A new submerged membrane photocatalysis reactor (SMPR) for fulvic acid removal using a nano-structured photocatalyst / J. Fu, M. Ji, Z. Wang, L. Jin, D. // J. Hazard. Mater. – 2006. – V. 131. – P. 238 – 242.

Mozia S., Morawski A.W. Photocatalytic membrane reactor (PMR) coupling photocata­lysis and membrane distillation—Effectiveness of removal of three azo dyes from water // Catal. Today – 2007. – V. 129. – Р. 3 – 8.

The combination of heterogeneous photocatalysis with chemical and physical operations: A tool for improving the photoprocess performance / V. Augugliaro, M. Litter, L. Palmisano, J. Soria // J. Photochem. Photobiol. C : Photochem. Rev.  – 2006. – V. 7. – P. 127 – 144.

Photocatalyzed degradation of polymers in aqueous semiconductor suspensions. 3. Photooxidation of a solid polymer: TiO2-blended poly(vinyl chloride) film / S. Horikoshi, N. Serpone, Y. Hisamatsu, H. Hidaka // Environ. Sci. Technol. – 1998. – V. 32. – P. 4010 – 4018.

Gesenhues U. Influence of titanium dioxide pigments on the photodegradation of poly(vinyl chloride) // Polym. Degrad. Stabil. – 2000. – V. 68. – P. 185 – 196.

UNEP (The US Global Change research information office), Plastic Photodegradation, 1998 (htpp://gcrio.org/UNEP1998/UNEP98p61.html).

Choi H., Stathatos E., Dionysiou D.D. Photocatalytic TiO2 films and membranes for the development of efficient wastewater treatment and reuse systems // Desalination. – 2007. − V. 202. – P. 199 – 206.

Bae T.-H., Tak T.-M. Effect of TiO2 nanoparticles on fouling mitigation of ultrafiltration membranes for activated sludge filtration // J. Membr. Sci. – 2005. – V. 249. – P. 1 – 8.

Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation of organic contaminants in water / G. Balasubramanian, D.D. Dionysiou, M.T. Suidan,  I. Baudin, J.-M. Laı̂né // Applied Catalysis B: Environmental. – 2004. – V. 47. – P. 73 – 84.

Photocatalytic oxidation of trichloroethylene and carbon tetrachloride using titanium dioxide filter as a catalyst / T.S. Wiltovsky, R.D. Howerton, S.B. Lalvani, V. Zamansky // Energy Sources. – 2001. – V. 23. – P. 845 – 852.

Sobczynski A., Duczmal L., Zmudzinski W. Phenol destruction by photocatalysis on TiO2: an attempt to solve the reaction mechanism // J. Mol. Catal.A: Chem. – 2004. – V. 213. – P. 225 – 230.

The influence of pH and cadmium sulfide on the photocatalytic degradation of 2-chloro­phenol in titanium dioxide suspensions / R.A. Doong, C.H. Chen, R.A. Maithreepala, S.M. Chang // Water Res. – 2001. – V. 35. – P. 2873 – 2880.

Photocatalytic degradation of 2-chloro and 2-nitrophenol by titanium dioxide suspensions in aqueous solution / K.H. Wang, Y.H. Hsieh, M.Y. Chou, C.Y. Chang // Appl. Catal. B: Environ. – 1999. – V. 21. – P. 1 – 8.

Shengcong Liufu, Hanning Xiao, Yuping Li. Adsorption of poly(acrylic acid) onto the surface of titanium dioxide and the colloidal stability of aqueous suspension // J. Colloid Interface Sci. – 2005. – V. 281. – P.155 – 163.

Photocatalytic water treatment with different TiO2 nanoparticles and hydrophilic/hydrophobic layer silicate adsorbents /I. Ilisz, A. Dombi, K. Mogyorósy, I. Dé­kány // Colloids and Surfaces A: Physicochem. Eng. Aspects. – 2004. – V. 230, № 7. – P. 89 – 97.

Опубліковано
2008-07-30
Як цитувати
Rolya, E. A., Kochkodan, V. M., & Goncharuk, V. V. (2008). Preparation and properties of the photocatalytic-active membrane with immobilized TiO2 for water treatment from phenol and its derivatives. Поверхня, (14), 344-353. вилучено із http://surfacezbir.com.ua/index.php/surface/article/view/290
Розділ
Наноматеріали і нанотехнології