Порошки кристалічного дигідрофосфату калію (KDP)
Анотація
Розглядається використання кристалів фероелектрика KDP (фосфати та арсенати калію, рубідію, цезію) та їх дейтерованих аналогів у різних галузях, у тому числі у створенні електрооптичних пристроїв та як поглинаючих водень. Описуються фізичні властивості KDP - кристалів, зміна їхніх властивостей поблизу температури фазового переходу, а також методи одержання нанокристалів KDP та їх застосування в біомедицині.
Також у роботі вказано: фазовий перехід у кристалах KDP, що відбувається близько кімнатної температури і виявляється у зміні їх фізичних властивостей, таких як діелектрична проникність, оптичні властивості та теплоємність. Крім того, наближення до температури фазового переходу викликає зміну параметрів гратки кристала, що може привести до появи аномальних ефектів.
Розглянута структура елементарної комірки дигідрофосфату калію (KH2PO4). Побудовані графіки температурної залежності параметру порядку спонтанної поляризації та графіки температурної залежності конфігураційної теплоємності кристала в області фазового переходу та побудовані графіки температурної залежності зворотної та прямої діелектричної сприйнятливості. А також побудовані графіки параметру порядку, що характеризує ступінь спонтанної поляризації для різних температур, залежно від напруженості зовнішнього електричного поля.
Посилання
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